It really depends on how stretchy Spidey's web is as it's fired, which has varied dramatically when drama was called for. What further muddies matters is that Peter had a cold right as this was going on, making note that his reflexes were a little off. There's plenty of wiggle room.
Gwen Stacy's "<snap>" is the same thing as the "jounced the limb" moment from Knowles' "A Separate Peace". I got an A on a high school paper that mentioned this (even thought I got an "obscure reference?" note in red from my teacher for mentioning Spidey as an example
).
As applied to Superman, what amuses me is that folks reject Byrne's pseudo physics pertaining to Superman's bio-aura, even though it goes a long way toward explaining how he can semi-realistically lift battleships -and- keeps the garment industry alive replacing tattered capes.